The answer to this question is “It depends.”
There are many reasons why SSO can improve security. A single sign-on solution can simplify username and password management for both users and administrators. Users no longer have to keep track of different sets of credentials and can simply remember a single more complex password. SSO often enables users to just get access to their applications much faster.
SSO can also cut down on the amount of time the help desk has to spend on assisting users with lost passwords. Administrators can centrally control requirements like password complexity and multi-factor authentication (MFA). Administrators can also more quickly relinquish login privileges across the board when a user leaves the organization.
Single Sign-On does have some drawbacks. For example, you might have applications that you want to have locked down a bit more. For this reason, it would be important to choose an SSO solution that gives you the ability to, say, require an additional authentication factor before a user logs into a particular application or that prevents users from accessing certain applications unless they are connected to a secure network.